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A novel composite hydrogel bead composed of sodium alginate (SA) and aldehyde cellulose nanocrystal (DCNC) was developed for antibiotic remediation through a one-step cross-linking process in a calcium chloride bath. Structural and physical properties of the hydrogel bead, with varying composition ratios, were analyzed using techniques such as BET analysis, SEM imaging, tensile testing, and rheology measurement. The optimal composition ratio was found to be 40% (SA) and 60% (DCNC) by weight. The performance of the SA–DCNC hydrogel bead for antibiotic remediation was evaluated using doxycycline (DOXY) and three other tetracyclines in both single- and multidrug systems, yielding a maximum adsorption capacity of 421.5 mg g−1 at pH 7 and 649.9 mg g−1 at pH 11 for DOXY. The adsorption mechanisms were investigated through adsorption studies focusing on the effects of contact time, pH, concentration, and competitive contaminants, along with X-ray photoelectron spectroscopy analysis of samples. The adsorption of DOXY was confirmed to be the synergetic effects of chemical reaction, electrostatic interaction, hydrogen bonding, and pore diffusion/surface deposition. The SA–DCNC composite hydrogel demonstrated high reusability, with more than 80% of its adsorption efficiency remaining after five cycles of the adsorption–desorption test. The SA–DCNC composite hydrogel bead could be a promising biomaterial for future antibiotic remediation applications in both pilot and industrial scales because of its high adsorption efficiency and ease of recycling.more » « less
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Abstract Prior studies in multilingual language modeling (e.g., Cotterell et al., 2018; Mielke et al., 2019) disagree on whether or not inflectional morphology makes languages harder to model. We attempt to resolve the disagreement and extend those studies. We compile a larger corpus of 145 Bible translations in 92 languages and a larger number of typological features.1 We fill in missing typological data for several languages and consider corpus-based measures of morphological complexity in addition to expert-produced typological features. We find that several morphological measures are significantly associated with higher surprisal when LSTM models are trained with BPE-segmented data. We also investigate linguistically motivated subword segmentation strategies like Morfessor and Finite-State Transducers (FSTs) and find that these segmentation strategies yield better performance and reduce the impact of a language’s morphology on language modeling.more » « less
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Many techniques in modern computational linguistics and natural language processing (NLP) make the assumption that approaches that work well on English and other widely used European (and sometimes Asian) languages are “language agnostic” – that is that they will also work across the typologically diverse languages of the world. In high-resource languages, especially those that are analytic rather than synthetic, a common approach is to treat morphologically-distinct variants of a common root (such as dog and dogs) as completely independent word types. Doing so relies on two main assumptions: that there exist a limited number of morphological inflections for any given root, and that most or all of those variants will appear in a large enough corpus (conditioned on assumptions about domain, etc.) so that the model can adequately learn statistics about each variant. Approaches like stemming, lemmatization, morphological analysis, subword segmentation, or other normalization techniques are frequently used when either of those assumptions are likely to be violated, particularly in the case of synthetic languages like Czech and Russian that have more inflectional morphology than English. Within the NLP literature, agglutinative languages like Finnish and Turkish are commonly held up as extreme examples of morphological complexity that challenge common modelling assumptions. Yet, when considering all of the world’s languages, Finnish and Turkish are closer to the average case in terms of synthesis. When we consider polysynthetic languages (those at the extreme of morphological complexity), even approaches like stemming, lemmatization, or subword modelling may not suffice. These languages have very high numbers of hapax legomena (words appearing only once in a corpus), underscoring the need for appropriate morphological handling of words, without which there is no hope for a model to capture enough statistical information about those words. Moreover, many of these languages have only very small text corpora, substantially magnifying these challenges. To this end, we examine the current state-of-the-art in language modelling, machine translation, and predictive text completion in the context of four polysynthetic languages: Guaraní, St. Lawrence Island Yupik, Central Alaskan Yup’ik, and Inuktitut. We have a particular focus on Inuit-Yupik, a highly challenging family of endangered polysynthetic languages that ranges geographically from Greenland through northern Canada and Alaska to far eastern Russia. The languages in this family are extraordinarily challenging from a computational perspective, with pervasive use of derivational morphemes in addition to rich sets of inflectional suffixes and phonological challenges at morpheme boundaries. Finally, we propose a novel framework for language modelling that combines knowledge representations from finite-state morphological analyzers with Tensor Product Representations (Smolensky, 1990) in order to enable successful neural language models capable of handling the full linguistic variety of typologically variant languages.more » « less
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null (Ed.)Many techniques in modern computational linguistics and natural language processing (NLP) make the assumption that approaches that work well on English and other widely used European (and sometimes Asian) languages are “language agnostic” – that is that they will also work across the typologically diverse languages of the world. In high-resource languages, especially those that are analytic rather than synthetic, a common approach is to treat morphologically-distinct variants of a common root (such as dog and dogs) as completely independent word types. Doing so relies on two main assumptions: that there exist a limited number of morphological inflections for any given root, and that most or all of those variants will appear in a large enough corpus (conditioned on assumptions about domain, etc.) so that the model can adequately learn statistics about each variant. Approaches like stemming, lemmatization, morphological analysis, subword segmentation, or other normalization techniques are frequently used when either of those assumptions are likely to be violated, particularly in the case of synthetic languages like Czech and Russian that have more inflectional morphology than English. Within the NLP literature, agglutinative languages like Finnish and Turkish are commonly held up as extreme examples of morphological complexity that challenge common modelling assumptions. Yet, when considering all of the world’s languages, Finnish and Turkish are closer to the average case in terms of synthesis. When we consider polysynthetic languages (those at the extreme of morphological complexity), even approaches like stemming, lemmatization, or subword modelling may not suffice. These languages have very high numbers of hapax legomena (words appearing only once in a corpus), underscoring the need for appropriate morphological handling of words, without which there is no hope for a model to capture enough statistical information about those words. Moreover, many of these languages have only very small text corpora, substantially magnifying these challenges. To this end, we examine the current state-of-the-art in language modelling, machine translation, and predictive text completion in the context of four polysynthetic languages: Guaraní, St. Lawrence Island Yupik, Central Alaskan Yup’ik, and Inuktitut. We have a particular focus on Inuit-Yupik, a highly challenging family of endangered polysynthetic languages that ranges geographically from Greenland through northern Canada and Alaska to far eastern Russia. The languages in this family are extraordinarily challenging from a computational perspective, with pervasive use of derivational morphemes in addition to rich sets of inflectional suffixes and phonological challenges at morpheme boundaries. Finally, we propose a novel framework for language modelling that combines knowledge representations from finite-state morphological analyzers with Tensor Product Representations (Smolensky, 1990) in order to enable successful neural language models capable of handling the full linguistic variety of typologically variant languages.more » « less
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